Inorganic Chemistry

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Now in @InorgChem! Read about heteroleptic bimetallic complexes exhibiting strong metallophilic interactions obtained using simple synthetic procedures. In the case of silver(I) ions, an unprecedented paddlewheel-like structure was achieved:

Now in @InorgChem! Spin crossover in a Co-iminosemiquinonate complex & versatility in Co oxidation/spin state & ligand oxidation/protonation state, new from @ColetteBoskovic @unimelb #SpinCrossover #RedoxActiveLigands Read it here:

Check out the latest in @InorgChem! New Uranyl Naphthylsalophen and Pyrasal Complexes with Oxo Ligands Acting as Hydrogen Bond Acceptors by @anniegorden's group at @TTUChemGrad:

The cover of @InorgChem this week accompanies the article "Redox Noninnocent Copper(I) Complex Where Metal Is a Spectator and Ligand Is an Actor in the Glaser Coupling Reaction of Alkynes". View it here:

Nominations are open until January 11th for the 2025 ACS Organic & Inorganic Au Rising Stars! If you're in the first 8 years of your career, nominate yourself or a peer to be featured in the journal's upcoming Special Issue. Find out more:

New in @InorgChem! The Alan Balch Lab expands the understanding of gold(I) chemistry and ligand design: #Chemistry #GoldComplexes #CoordinationChemistry

Now in @InorgChem! @Mechanochem for the rapid and green synthesis of highly conductive dhta-alkali polymers, showing that more (metal) doesn't always mean better: @LFM_RBI @institutrb @RBI_AppSustChem @p021_desy

Now in @InorgChem! The exsolution mechanism of Ag-NPs from Ag-doped perovskites is unveiled. Ag-NPs remain stable up to 800°C, which is crucial for the application of silver-decorated materials at high temperature:

The cover of @InorgChem this week accompanies the article "Photoexcitation and One-Electron Reduction Processes of a CO2 Photoreduction Dyad Catalyst Having a Zinc(II) Porphyrin Photosensitizer". View it here:

New in @InorgChem! Read about a new approach enabling the direct hydrogenation of nitriles to primary amines without the need for additives. @OmcmlB @serbonline @CSIRCSMCRI1

New layered AlPO₄ material HPM-3 discovered! Precursor to the so far unknown neutral AlPO₄ with JSN topology through a low T topotactic condensation. Check out the full details in @InorgChem here: @mcplatano @HuajianY @icmm_csic @ICP_CSIC @CSIC

The cover art of @InorgChem this week accompanies the article "Fluoride Ion Storage and Conduction Mechanism in Fluoride Ion Battery Positive Electrode, Ruddlesden–Popper-Type Layered Perovskite La1.2Sr1.8Mn2O7 Crystal". View it here:

Check out the new paper in @InorgChem revealing spin-flip luminescence in a chromium(III) metallosupramolecular cage providing new perspective on Cr(III) chemistry: @_juanrajimenez

The cover art of @InorgChem this week accompanies the article "Binuclear Coordination Assemblies of Metal Tetraphenylporphyrins (M = Mn, Fe, and In) with Anionic Thioindigo Bridges as Promising Magnetic Systems with Tunable Properties". Read it here:

Now in @InorgChem! Research from @kageyamalab shows the well-defined {100} facets of BaTiO3 cubes promote surface reactions during topochemical reduction, facilitating O/H exchange to form BaTiO2.3H0.7 with the highest reported H content:

More great @InorgChem from across the Periodic Table! Lu et al. demonstrate that symmetry trapping suppresses ferroelectricity in Dion-Jacobson layered perovskite oxides Cs(La,Nd)Nb2O7:

LAST CALL FOR NOMINATIONS The 2025 Inorganic Chemistry Lectureship recognizes an early career researcher who has demonstrated creativity and impact in leading research in inorganic chemistry. Submit your nomination by December 1st! @ACSINORDivision

The cover art of @InorgChem this week represents a lanthanide phosphinate square grid, encapsulating a carbonate anion, as discussed in

The 2025 Inorganic Chemistry Lectureship recognizes an early career researcher who has demonstrated creativity and impact in leading research in inorganic chemistry. Find out more and submit your nomination: @ACSINORDivision